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铁道科学与工程学报

JOURNAL OF RAILWAY SCIENCE AND ENGINEERING

Vol. 17    No. 2    April 2007

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Effect of Ca on crystallization of Mg-based master
alloy containing spherical quasicrystal
ZHANG Jin-shan(张金山), DU Hong-wei(杜宏伟), LU Bin-feng(卢斌峰),
ZHANG Yan(张 焱), LIANG Wei(梁 伟),
XU Chun-xiang(许春香), LU Feng-lei(陆风雷)

School of Materials Science and Engineering, Taiyuan University of Technology,
Taiyuan 030024, China

Abstract:Spherical icosahedral quasicrystalline phase (I-phase) was obtained by introducing Ca into Mg-Zn-Y alloy under conventional casting conditions. Due to the addition of Ca, Mg45Zn50Y4.5Ca0.5 primary I-phase, which is thermodynamically stable and homogeneously distributed, was generated instead of decahedral quasicrystalline phase during the solidification process; the morphology of primary I-phase in the solidification microstructure changed from petal-like one (60−80 μm) to spherical one (≤15 μm). When the mass fraction of Ca reaches 0.05%, spherical I-phase with the largest quantity, highest spheroidization rate and highest circular degree can be obtained. Meanwhile, due to the changed morphology and the decreased size of primary I-phase, the hardness of Mg-Zn-Y-Ca master alloy is reduced. The application of spherical I-phase as particulate reinforced phase provides great opportunities for the improvement of strength and toughness of magnesium alloys.

 

Key words: magnesium alloy; Ca; spherical quasicrystal; crystallization; microstructure

ISSN 1672-7029
CN 43-1423/U

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