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铁道科学与工程学报

JOURNAL OF RAILWAY SCIENCE AND ENGINEERING

Vol. 17    No. 3    June 2007

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Preparation of Y2O3׃Eu3+ phosphor by molten salt assisted method
HUANG Yan(黄 燕)1, 2, 3, YE Hong-qi(叶红齐)1,
ZHUANG Wei-dong(庄卫东)2, HU Yun-sheng(胡运生)2, ZHAO Chun-lei(赵春雷)2,
LI Cui(李 萃)2, GUO Song-xia(郭松霞)2

1. School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China;
2. National Engineering Research Center for Rare Earth Materials, General Research Institute for Nonferrous Metals,
Beijing 100088, China;
3. Department of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang 414000, China

Abstract:A kind of fine and quasi-spherical Y2O3׃Eu3+ phosphor was prepared by firing a preparative precursor at 1 200 ℃ for 2 h with the molten salts of Na2CO3, S and NaCl. The precursor was obtained by homogeneous precipitation of yttrium and europium with oxalic acid when using EDTA, citric acid or starch as complexant. The structure and morphology of the phosphors were characterized by XRD and SEM, respectively. The influence of complexing environment, firing temperature and molten salts on formation of the phosphor Y2O3׃Eu3+ was discussed. The result show that the prepared Y2O3׃Eu3+ phosphor is of quasi-spherical structure with size of 2−3 μm. Its luminescent intensity is 30% higher than that of the same phosphor prepared by the same procedure but without molten salts, and is 5% higher than that of commercial Y2O3׃Eu3+ red phosphor.

 

Key words: Y2O3׃Eu3+; molten salt; homogeneous precipitation; morphology; luminescent property

ISSN 1672-7029
CN 43-1423/U

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