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铁道科学与工程学报

JOURNAL OF RAILWAY SCIENCE AND ENGINEERING

Vol. 17    No. 5    October 2007

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Crystallization, morphology and luminescent properties of YAG:Ce3+phosphor powder prepared by polyacrylamide gel method
LIU Chun-jia(刘春佳), YU Rui-min(于瑞敏), XU Zhi-wei(许志伟), CAI Jing(蔡 靖), YAN Xing-huang(严星煌), LUO Xue-tao(罗学涛)

Department of Materials Science and Engineering, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China

Abstract:A novel synthesis process, based on the polyacrylamide gel method, was used to prepare Ce-doped YAG phosphor powders. Effects of heat treatment parameters, temperature and holding time, the fluxes, and atmosphere on microstructure and particle morphology as well as luminescent properties of YAG:Ce3+ phosphor powders were studied by X-ray powder diffractometry, scanning electron microscopy, and fluorescence spectrophotometry. The results show that the formation temperature (1 000 ℃) of pure YAG phase is significant low when being synthesized by the polyacrylamide gel method, compared with solid-state reaction. For luminescent properties, the intensity of emission of YAG:Ce3+ phosphor increases steadily with increasing temperature from 900 ℃ to 1 300 ℃ and prolonging holding time from 100 min to 400 min. But blue shift phenomenon is observed for 400 min calcination. Fluxes as BaF2 and H3BO3 can enhance the intensity of emission of phosphor due to the improvement of crystallization of YAG and the stabilization of trivalence cerium ion in YAG host lattice at high temperature. Weak reduction atmosphere can contribute to improvement of the emission intensity of YAG:Ce3+ phosphor powders.

 

Key words: YAG phosphor; polyacrylamide gel; crystallization; morphology; luminescent properties

ISSN 1672-7029
CN 43-1423/U

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