您目前所在的位置:首页 - 期刊简介 - 详细页面

铁道科学与工程学报

JOURNAL OF RAILWAY SCIENCE AND ENGINEERING

Vol. 11    No. 6    December 2001

[PDF Download]    [Flash Online]

    

Removal of sulfur in coke oven gas
by mixing ZnO-based additive into coal
GUO Zhan-cheng(郭占成),  TANG Hui-qing(唐惠庆),  YE Shu-feng(叶树锋)

Institute of Process Engineering, Chinese Academy of
Sciences,Beijing 100080, P.R.China

Abstract: A new technology for recycling EAF dust and removal of sulfur from coking oven gas was investigated. The new technology does not need to set up special equipment to treat COG (coke oven gas), and it is only acquired by mixing the ZnO-base additive into the coke coal. In the stage of pyrolysis of the coal volatile, ZnO of the additive combines with H2S, CS2, COS and C2H2SH of coal gas, forming ZnS in coal char. In the stage of coking of the coal char, Zn is gasified with S, then the gas Zn react with H2S, CS2, COS and C2H2SH, forming ZnS in coal gas and depositing as dust. After the collected ZnS dust was regenerated, it can be recycling as the additive again. The sulfur in coal gas can be completely removed if the mole ratio of the added Zn to the volatilized S is more than 1, and the sulfur in coke is also slightly decreased comparing with the coke without the additive.  The EAF dust containing ZnO and Fe2O3can be the base material of the desulfurizing additive.

 

Key words:  sulfur removal; coal gas; coking; sulfur sorbent; EAF dust

ISSN 1672-7029
CN 43-1423/U

主管:中华人民共和国教育部 主办:中南大学 中国铁道学会 承办:中南大学
湘ICP备09001153号 版权所有:《铁道科学与工程学报》编辑部
------------------------------------------------------------------------------------------
地 址:湖南省长沙市韶山南路22号 邮编:410075
电 话:0731-82655133,82656174   传真:0731-82655133   电子邮箱:jrse@mail.csu.edu.cn