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铁道科学与工程学报

JOURNAL OF RAILWAY SCIENCE AND ENGINEERING

Vol. 13    No. 5    October 2003

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Inhibition behavior for copper corrosion by photoelectrochemical methods
XU Qun-jie(徐群杰), ZHOU Guo-ding(周国定)

Electrochemical Research Group, Shanghai University of Electric Power, Shanghai 200090, China

Abstract:The application of photoelectrochemical methods in the inhibition effects for copper corrosion was described. The methods include cyclic voltammetry photocurrent measurements, intensity modulated photocurrent spectrum(IMPS) and laser-scanning photoelectrochemical microscopic method(PEM) which have been applied to the evaluation of inhibitors and inhibition behavior. The inhibition effect of BTA for copper corrosion is better than that of 4CBTA, 5CBTA, CBT-1, PTD, BT-250, CBTME and CBTBE at the same concentration. The inhibition mechanism of the derivatives of BTA with —COOH group(4CBTA, 5CBTA, CBT-1) is different from those with estergroup(CBTME, CBTBE).

 

Key words: copper; corrosion; inhibitors; inhibition mechanism;photoelectrochemical method

ISSN 1672-7029
CN 43-1423/U

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