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铁道科学与工程学报

JOURNAL OF RAILWAY SCIENCE AND ENGINEERING

Vol. 19    No. 6    December 2009

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Megahertz magneto-dielectric properties of nanosized NiZnCo ferrite from CTAB-assisted hydrothermal process
SHEN Xiang(沈 翔)1, 2, WANG Yan-xin(王焰新)3, YANG Xiang(杨 祥)1, 2,
XIA Yong(夏 勇)2, ZHUANG Jian-feng(庄剑锋)2, TANG Pei-duo(唐培朵)

1. Engineering Research Center of Nano-Geomaterials of Ministry of Education,
China University of Geosciences, Wuhan 430074, China;
2. Faculty of Material Science and Chemical Engineering, China University of Geosciences, Wuhan 430074, China;
3. School of Environmental Studies, China University of Geosciences, Wuhan 430074, China

Abstract:A simple hydrothermal route with cetyltrimethyl ammonium bromide (CTAB) was proposed for directly synthesizing single-crystalline NiZn ferrite at 160 ℃. X-ray diffraction patterns and micrographs indicate that products consist of spinel ferrite nanogranulars. The dielectric constant of NiZnCo ferrite is about 11 and the imaginary part of complex permittivity is 1.3. The saturation magnetization (Ms) of NiZn ferrite improves from 0.041 to 0.074 A·m2/g for Ni0.49Zn0.5Co0.01Fe1.98O4. The dielectric contant of NiZn ferrite increases from 7 to 11 with a cobalt stoichiometry of 0.01. The real part μ′ of complex permeability for NiZnCo ferrite reaches 3 at 1 GHz. The imaginary part μ″ of NiZnCo ferrite has a value higher than 1.2 within 0.7−3.0 GHz. Through the incorporation of the magnetic fillers, the low dielectric constant of the composites may meet the requirements of impedance matching to achieve the maximal absorption of the electromagnetic energy in megahertz frequency range.

 

Key words: NiZnCo ferrite; hydrothermal; permeability; permittivity; saturation magnetization

ISSN 1672-7029
CN 43-1423/U

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