您目前所在的位置:首页 - 期刊简介 - 详细页面

铁道科学与工程学报

JOURNAL OF RAILWAY SCIENCE AND ENGINEERING

Vol. 19    No. 6    December 2009

[PDF Download]    [Flash Online]

    

Volume sequences of characteristic atoms separated from
experimental volumes of AuCu and AuCu3 compounds
XIE You-qing(谢佑卿)1, 2, 3, LIU Xin-bi(刘心笔)1, LI Xiao-bo(李晓波)4,
PENG Hong-jian(彭红建)1, NIE Yao-zhuang(聂耀庄)1

1. School of Materials Science and Engineering, Central South University, Changsha 410083, China;
2. Powder Metallurgy Research Institute, Central South University, Changsha 410083, China;
 3. State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China;
4. College of Mechanical Engineering, Xiangtan University, Xiangtan 411105, China

Abstract:The systematic science of alloys (SSA) is a framework of the total energy and total volume able to be separated. The volume sequences of characteristic atoms at the central sites of the basic clusters in the fcc-based Au-Cu system are separated out from the experimental volumes of L10-AuCu and L12-AuCu3 compounds at room temperature only, by nine volume V-functions. From these volume sequences, the volumes, volumes of formation, ordering (excess) volumes and volume mismatch degrees of the L10-AuCu, L12-AuCu3 and L12-Au3Cu compounds, Au3Cu-, AuCu- and AuCu3-type ordered alloys with maximal ordering degree, and disordered Au1−xCux alloys are calculated. Among these functions, only ordering volumes of the compounds and ordered alloys obtained by the 6th V-function are negative, i.e., the destruction of the superlattice is accompanied by an increase in volume, which is identical with the experimental results. Accompanying conclusions, the different descriptions of volumetric properties between traditional alloy theories and SSA framework are discussed.

 

Key words: systematic science of alloys; Au-Cu system; atomic volume; volume of formation; ordering volume; volume mismatch

ISSN 1672-7029
CN 43-1423/U

主管:中华人民共和国教育部 主办:中南大学 中国铁道学会 承办:中南大学
湘ICP备09001153号 版权所有:《铁道科学与工程学报》编辑部
------------------------------------------------------------------------------------------
地 址:湖南省长沙市韶山南路22号 邮编:410075
电 话:0731-82655133,82656174   传真:0731-82655133   电子邮箱:jrse@mail.csu.edu.cn