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铁道科学与工程学报

JOURNAL OF RAILWAY SCIENCE AND ENGINEERING

Vol. 17    Special 1    November 2007

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Hydrogen desorption behaviors of zirconium hydride inoxygen containing atmosphere
CHEN Wei-dong(陈伟东), WANG Jian-wei(王建伟), WANG Li-jun(王力军), LU Shi-gang(卢世刚)

Division of Mineral Resources, Metallurgy and Materials, General Research Institute for Nonferrous Metals,
Beijing 100088, China

Abstract:Hydrogen desorption behaviors of zirconium hydride at temperature range of 100−900 ℃ in mixture gases of helium and oxygen was studied by gas phase analysis(GPA). Meanwhile, the morphologies of the oxide scale formed on the surface of zirconium hydride were analyzed by scanning electron microscopy(SEM). The hydrogen desorption is retarded effectively when zirconium hydride is exposed to an oxygen containing atmosphere. Hydrogen desorption in mixed gas of helium and oxygen starts at 525 ℃ and reaches maximum at 660 ℃ and ends eventually at 800 ℃. No hydrogen desorption is found at the temperature range from 800 ℃ to 900 ℃. An oxide scale with approximately 20 μm in thickness formed on the surface of zirconium hydride acts as an effective diffusion barrier.

 

Key words: zirconium hydride; gas phase analysis(GPA); hydrogen desorption; oxide scale

ISSN 1672-7029
CN 43-1423/U

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